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Ionic liquids are excellent substitutes for
traditional organic solvents in many typical
organic reactions, often producing higher
selectivities as well as higher yields, and
enhancing the reaction rate. Additionally, they
can serve as catalyst immobilization for the easy
recycling of homogeneous catalysts without need for
special functionalization, and have been successfully
employed as electrolytes in electrochemistry. "Tailor-made"
solvents (optimization of the ionic liquid's characteristics)
can be achieved through a broad choice of anion and cation combinations.
Ionic liquids are attractive solvents as they are non-volatile,
non-flammable, have a high thermal stability and are relatively
inexpensive to manufacture. They usually exist as liquids well below
room temperature up to a temperature as high as 200oC.
The key point about ionic liquids is that they are liquid salts,
which means they consist of a salt that exists in the liquid phase.
They are not simply salts dissolved in liquid. Usually one or both
of the ions is particularly large and the cation has a low degree of
symmetry, these factors result in ionic liquids having a reduced lattice
energy and hence lower melting points.Many ionic liquids have even been
developed for specific synthetic problems. For this reason, ionic liquids
have been termed "designer solvents".
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